| session |
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{'distortionless-enhancement-with-polarization-transfer': 14}, 'license_id': {'CC0 1.0 Universal ': 14}}, 'results': [{'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s863.d4277', 'id': 'nmrxiv-d4277', 'inchi': 'InChI=1S/C25H44O3Si/c1-23(2,3)29(6,7)28-17-14-16-8-9-18-19-10-11-21(26)24(19,4)13-12-20(18)25(16,5)22(27)15-17/h14,17-22,26-27H,8-13,15H2,1-7H3/t17-,18?,19?,20?,21+,22+,24+,25+/m1/s1', 'inchi_key': 'BYIZMXXEFLVSTQ-OGVWNADFSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:45:23.731817', 'metadata_modified': '2025-04-19T13:44:34.213606', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeiv-022b_c1_c17_diol_c3_otbdms_08-19-2024_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL date: 2024-08-19T17:50:13.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/1 phc0: -20.90166 phc1: 41.54116 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1505 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 19607.843137254902 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-08-20T03:03:49.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/10 phc0: -21.62674 phc1: 40.71448 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1502 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 50 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 19607.843137254902 experimentNumber: 10 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-08-20T01:45:21.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/2 phc0: -17.6228 phc1: -79.96218 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 47.327373068158664 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1477 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 500 pulseSequence: udeft spectralWidth: 283.964238408952 numberOfPoints: 7 relaxationTime: 4 acquisitionTime: 0.00008399999999999987 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 23584.90566037736 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2024-08-20T01:48:15.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/3 phc0: 65.41486 phc1: 171.6144 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 26.717599740426834 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1485 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 32 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 7 relaxationTime: 2 acquisitionTime: 0.0001488000000005666 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 23584.90566037736 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-08-20T01:56:06.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/4 phc0: 44.98304 phc1: 227.4534 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 39.439477556902666 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.1506 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 7 relaxationTime: 2 acquisitionTime: 0.0001007999999997346 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 23584.90566037736 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-08-20T02:11:28.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 1.62294702731525 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1497 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 9 relaxationTime: 1.5 acquisitionTime: 0.0006160000000000007 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 19607.843137254902 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2024-08-20T02:33:04.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1503 spectrumSize: 4096,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 19607.843137254902 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2024-08-20T02:35:02.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1508 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 19607.843137254902 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2024-08-20T02:57:37.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 4.998676844130975 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1505 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 4 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 3 relaxationTime: 2 acquisitionTime: 0.00020000000000000004 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 19607.843137254902 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4 date: 2024-08-20T03:00:53.000Z isFt: true name: AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL/9 phc0: 0,180 phc1: 0,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 2.4993384220654873 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: tocsy groupDelay: 76 temperature: 298.1502 spectrumSize: 2048,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 2 pulseSequence: mlevphpr.2 spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0004000000000000001 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 19607.843137254902 experimentNumber: 9 acquisitionScheme: States-TPPI linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'CC(C)(C)[Si](C)(C)O[C@@H]1C=C2CCC3C4CC[C@H](O)[C@@]4(C)CCC3[C@@]2(C)[C@@H](O)C1', 'state': 'active', 'title': 'AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4277', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-04-19T13:44:34.230105', 'format': 'HTML', 'hash': '', 'id': '2d7ad322-8716-458c-a3c0-24c27b141bff', 'last_modified': None, 'metadata_modified': '2025-04-19T13:44:34.220551', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEIV-022B_C1_C17_diol_C3_OTBDMS_08.19.2024_FULL.dept', 'package_id': 'nmrxiv-d4277', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4277', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1485'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '32'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp135'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '160.305598442561'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '7'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '18885417-4175-4372-9ea4-ccd2756bfa09'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s858.d4233', 'id': 'nmrxiv-d4233', 'inchi': 'InChI=1S/C22H38O3Si/c1-21-11-10-18-16(17(21)8-9-19(21)24)7-6-14-12-15(23)13-20(22(14,18)2)25-26(3,4)5/h12,15-20,23-24H,6-11,13H2,1-5H3/t15?,16?,17?,18?,19-,20-,21-,22-/m0/s1', 'inchi_key': 'RNOPMFBADSIDRA-XLVMOJGQSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:45:18.977522', 'metadata_modified': '2025-04-19T13:44:29.673684', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeii-050b_full_nabh4_3oh_delta4_tmsc1_17oh_01_08_2024_full-dept1', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL date: 2024-01-08T22:51:30.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/1 phc0: -93.72746 phc1: 49.68005 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1491 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 24703.557312252968 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T04:42:32.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/2 phc0: -16.55622 phc1: -163.1828 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.991059602238 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1494 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 512 pulseSequence: udeft spectralWidth: 283.964238408952 numberOfPoints: 5 relaxationTime: 4 acquisitionTime: 0.00005599999999999992 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2024-01-09T04:49:15.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/3 phc0: -5.940369 phc1: 234.8051 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.991059602238 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9910888671875 temperature: 298.1491 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 283.964238408952 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00005599999999999992 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T05:02:05.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/4 phc0: -75.8622 phc1: 348.861 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.99247931054725 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9910888671875 temperature: 298.1513 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 256 pulseSequence: deptsp135 spectralWidth: 283.969917242189 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00005600000000000007 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 15625 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T05:09:34.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1504 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 24703.557312252968 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2024-01-09T05:20:13.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1494 spectrumSize: 4096,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 24703.557312252968 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2024-01-09T05:21:47.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1497 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 24703.557312252968 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2024-01-09T06:05:53.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.33245122942065 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1491 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 4 relaxationTime: 2 acquisitionTime: 0.00030000000000000003 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 24703.557312252968 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'C[C@]12CCC3C(CCC4=CC(O)C[C@H](O[Si](C)(C)C)[C@@]43C)C1CC[C@@H]2O', 'state': 'active', 'title': 'AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4233', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-04-19T13:44:29.686904', 'format': 'HTML', 'hash': '', 'id': 'c839756c-47d2-42c2-93f8-d40169c4bddc', 'last_modified': None, 'metadata_modified': '2025-04-19T13:44:29.678868', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL.dept', 'package_id': 'nmrxiv-d4233', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4233', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1491'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '128'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp90'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '283.964238408952'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '257cc3c4-35f9-4306-90e3-f26e889eaaf1'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s870.d4350', 'id': 'nmrxiv-d4350', 'inchi': 'InChI=1S/C25H44O3Si.C2H6/c1-23(2,3)29(6,7)28-17-14-16-8-9-18-19-10-11-21(26)24(19,4)13-12-20(18)25(16,5)22(27)15-17;1-2/h14,17-22,26-27H,8-13,15H2,1-7H3;1-2H3/t17-,18?,19?,20?,21+,22-,24+,25+;/m1./s1/i21D,22D;', 'inchi_key': 'UVCOMUSIWVTRAW-BZIGOVRDSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:44:49.285637', 'metadata_modified': '2025-04-19T13:44:04.470886', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeiv-086b_c1_c17_b_diol_c3_otbdms_deuterated_03-05-2025_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL date: 2025-03-06T04:36:29.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/1 phc0: -59.77311 phc1: 41.70211 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1502 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 200 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 23809.52380952381 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2025-03-06T06:50:30.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/10 phc0: -31.63126 phc1: 255.6108 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 40.07639961064025 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1515 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 32 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00009920000000037773 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 14662.756598240469 experimentNumber: 10 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2025-03-06T04:52:39.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/2 phc0: -20.12515 phc1: -98.73821 type: NMR Spectrum DECIM: 21706.6666666667 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 2H reverse: false solvent: CDCl3 dimension: 1 increment: 3.000307377442475 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9847564697266 temperature: 298.1499 spectrumSize: 65536 baseFrequency: 76.773 fieldStrength: 11.746718265873575 numberOfScans: 300 pulseSequence: zg2h spectralWidth: 12.0012295097699 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.002170666666666662 frequencyOffset: 460.6380000069521 originFrequency: 76.773460638 pulseStrength90: 1000 experimentNumber: 2 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2025-03-06T05:34:45.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/3 phc0: -86.08632 phc1: -33.94525 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 40.56631977270742 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1491 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 500 pulseSequence: udeft spectralWidth: 283.964238408952 numberOfPoints: 8 relaxationTime: 4 acquisitionTime: 0.00009799999999999985 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 14662.756598240469 experimentNumber: 3 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2025-03-06T05:50:07.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/4 phc0: -157.9219,-1.861549 phc1: -3.142803,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1507 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,199.776832419684 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,10689.412025001842 originFrequency: 500.132350611,125.768477938025 pulseStrength90: 23809.52380952381 experimentNumber: 4 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2025-03-06T06:11:43.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/5 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1505 spectrumSize: 4096,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 23809.52380952381 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2025-03-06T06:13:42.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1497 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 23809.52380952381 experimentNumber: 6 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2025-03-06T06:36:27.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/7 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.33245122942065 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1516 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 4 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 4 relaxationTime: 2 acquisitionTime: 0.00030000000000000003 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 23809.52380952381 experimentNumber: 7 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4 date: 2025-03-06T06:39:45.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/8 phc0: 0,180 phc1: 0,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 2.4993384220654873 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: tocsy groupDelay: 76 temperature: 298.1506 spectrumSize: 2048,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 2 pulseSequence: mlevphpr.2 spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0004000000000000001 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 23809.52380952381 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2025-03-06T06:47:37.000Z isFt: true name: AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL/9 phc0: -238.0224 phc1: 74.32818 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 59.159216335354 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.1495 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00006719999999982307 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 14662.756598240469 experimentNumber: 9 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'CC.[2H][C@]1(O)CCC2C3CCC4=C[C@@H](O[Si](C)(C)C(C)(C)C)C[C@@]([2H])(O)[C@]4(C)C3CC[C@@]21C', 'state': 'active', 'title': 'AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4350', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-04-19T13:44:04.494897', 'format': 'HTML', 'hash': '', 'id': 'a3a33442-b356-4f8e-bf18-d58af4447535', 'last_modified': None, 'metadata_modified': '2025-04-19T13:44:04.485538', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEIV-086B_C1_C17_b_diol_C3_OTBDMS_deuterated_03.05.2025_FULL.dept', 'package_id': 'nmrxiv-d4350', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4350', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1495'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '128'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp90'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '236.636865341416'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '471f045f-6da6-4948-ae7b-be641be8f8e6'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s862.d4269', 'id': 'nmrxiv-d4269', 'inchi': 'InChI=1S/C19H26O2/c1-18-11-10-15-13(14(18)8-9-16(18)20)7-6-12-4-3-5-17(21)19(12,15)2/h3-5,13-16,20H,6-11H2,1-2H3/t13?,14?,15?,16-,18-,19-/m0/s1', 'inchi_key': 'FXCSNJQTRVVMGS-QTOZILHFSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:44:03.026819', 'metadata_modified': '2025-04-19T13:43:22.678129', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeii-033b_nabh4_on_1_17_diketone_3opiv_dienone_a_ring_12_15_2023_full-dept1', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL date: 2023-12-15T23:28:30.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/1 phc0: 4.280609 phc1: 31.12811 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1497 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 24703.557312252968 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:24:39.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/2 phc0: -50.42865 phc1: -59.76928 type: NMR Spectrum DECIM: 634.666666666667 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 9.636795421118268 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1504 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 256 pulseSequence: udeft spectralWidth: 250.556680949075 numberOfPoints: 27 relaxationTime: 4 acquisitionTime: 0.0004125333333333332 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2023-12-16T03:31:47.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/3 phc0: 5.238708 phc1: 261.0771 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 59.159216335354 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.1494 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00006719999999982307 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:39:51.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/4 phc0: 33.82634 phc1: 193.4544 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 40.07639961064025 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1527 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00009920000000037773 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 15625 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:54:31.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1497 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 24703.557312252968 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2023-12-16T04:15:24.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1492 spectrumSize: 2048,1024 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 24703.557312252968 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2023-12-16T04:25:12.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1496 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 24703.557312252968 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2023-12-16T05:09:18.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 4.998676844130975 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1491 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 3 relaxationTime: 2 acquisitionTime: 0.00020000000000000004 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 24703.557312252968 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'C[C@]12C(=O)C=CC=C1CCC1C2CC[C@@]2(C)C1CC[C@@H]2O', 'state': 'active', 'title': 'AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4269', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-04-19T13:43:22.691278', 'format': 'HTML', 'hash': '', 'id': '78642064-c681-4057-8f8c-7c7266d56576', 'last_modified': None, 'metadata_modified': '2025-04-19T13:43:22.683310', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL.dept', 'package_id': 'nmrxiv-d4269', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4269', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1527'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '128'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp135'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '160.305598442561'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '00b3e48a-bf14-4c13-909c-c6708d393b1b'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s862.d4268', 'id': 'nmrxiv-d4268', 'inchi': 'InChI=1S/C19H26O2/c1-18-11-10-15-13(14(18)8-9-16(18)20)7-6-12-4-3-5-17(21)19(12,15)2/h3-5,13-16,20H,6-11H2,1-2H3/t13?,14?,15?,16-,18-,19-/m0/s1', 'inchi_key': 'FXCSNJQTRVVMGS-QTOZILHFSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:43:59.798431', 'metadata_modified': '2025-04-19T13:43:19.912900', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeii-033b_nabh4_on_1_17_diketone_3opiv_dienone_a_ring_12_15_2023_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL date: 2023-12-15T23:28:30.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/1 phc0: 4.280609 phc1: 31.12811 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1497 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 24703.557312252968 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:24:39.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/2 phc0: -50.42865 phc1: -59.76928 type: NMR Spectrum DECIM: 634.666666666667 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 9.636795421118268 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1504 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 256 pulseSequence: udeft spectralWidth: 250.556680949075 numberOfPoints: 27 relaxationTime: 4 acquisitionTime: 0.0004125333333333332 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2023-12-16T03:31:47.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/3 phc0: 5.238708 phc1: 261.0771 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 59.159216335354 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.1494 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00006719999999982307 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:39:51.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/4 phc0: 33.82634 phc1: 193.4544 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 40.07639961064025 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1527 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00009920000000037773 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 15625 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-12-16T03:54:31.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1497 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 24703.557312252968 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2023-12-16T04:15:24.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1492 spectrumSize: 2048,1024 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 24703.557312252968 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2023-12-16T04:25:12.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1496 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 24703.557312252968 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2023-12-16T05:09:18.000Z isFt: true name: AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 4.998676844130975 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1491 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 3 relaxationTime: 2 acquisitionTime: 0.00020000000000000004 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 24703.557312252968 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'C[C@]12C(=O)C=CC=C1CCC1C2CC[C@@]2(C)C1CC[C@@H]2O', 'state': 'active', 'title': 'AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4268', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-04-19T13:43:19.990463', 'format': 'HTML', 'hash': '', 'id': 'b8a6b24a-a5c1-4543-a9c2-752d9ffb76b9', 'last_modified': None, 'metadata_modified': '2025-04-19T13:43:19.963899', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEII-033B_NaBH4_on_1_17_diketone_3OPiv_dienone_A_ring_12_15_2023_FULL.dept', 'package_id': 'nmrxiv-d4268', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4268', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1494'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '128'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp90'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '236.636865341416'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '12883767-15c9-44f1-9f2c-0f09dd01bda5'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s864.d4287', 'id': 'nmrxiv-d4287', 'inchi': 'InChI=1S/C19H28O3/c1-18-8-7-15-13(14(18)5-6-16(18)21)4-3-11-9-12(20)10-17(22)19(11,15)2/h9,13-17,21-22H,3-8,10H2,1-2H3/t13?,14?,15?,16-,17-,18-,19-/m0/s1', 'inchi_key': 'LUWKGSHFDJJDAJ-MVJPESGUSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:43:56.443605', 'metadata_modified': '2025-03-22T14:43:56.443610', 'metadata_published': '2025-03-20 23:01:25', 'name': '9_aeiv-048b_1_a_oh_t_dmso_d2o_09-25-2024_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL date: 2024-09-25T20:23:29.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/1 phc0: -22.77374 phc1: 30.95786 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: DMSO dimension: 1 increment: 1.0523514676065842 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1498 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 20 relaxationTime: 1 acquisitionTime: 0.0009500000000008324 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 19607.843137254902 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-09-27T01:31:38.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/2 phc0: -72.92806 phc1: -5.299024 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: DMSO dimension: 1 increment: 7.0991059602238 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1508 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 250 pulseSequence: udeft spectralWidth: 283.964238408952 numberOfPoints: 41 relaxationTime: 4 acquisitionTime: 0.0005599999999999992 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 23584.90566037736 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2024-09-27T01:39:29.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/3 phc0: 24.29518 phc1: 241.0361 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: DMSO dimension: 1 increment: 59.159216335354 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.151 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00006719999999982307 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 23584.90566037736 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-09-27T01:42:23.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/4 phc0: 42.85634 phc1: 192.9539 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: DMSO dimension: 1 increment: 40.07639961064025 isComplex: true probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1475 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 32 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00009920000000037773 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 23584.90566037736 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-09-27T01:57:45.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: DMSO dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1501 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 19607.843137254902 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2024-09-27T02:19:21.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: DMSO dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1497 spectrumSize: 4096,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 16 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 19607.843137254902 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2024-09-27T02:21:52.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: DMSO dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1489 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 19607.843137254902 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2024-09-27T02:44:36.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: DMSO dimension: 2 increment: 4.998676844130975 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.15 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 4 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 3 relaxationTime: 2 acquisitionTime: 0.00020000000000000004 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 19607.843137254902 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4 date: 2024-09-27T02:59:50.000Z isFt: true name: 9_AEIV-048B_1_a_OH_T_DMSO_D2O_09.25.2024_FULL/9 phc0: 0,180 phc1: 0,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,1H reverse: false,false solvent: DMSO dimension: 2 increment: 2.4993384220654873 isComplex: false probeName: Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z) experiment: tocsy groupDelay: 76 temperature: 298.1483 spectrumSize: 2048,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 2 pulseSequence: mlevphpr.2 spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0004000000000000001 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 19607.843137254902 experimentNumber: 9 acquisitionScheme: States-TPPI linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4', 'num_resources': 1, 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'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z125869_0046 (CPP BBO 500S1 BB-H&F-D-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1475'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '32'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp135'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '160.305598442561'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '8d893ee9-163a-455d-848e-5ce19931306b'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s858.d4234', 'id': 'nmrxiv-d4234', 'inchi': 'InChI=1S/C22H38O3Si/c1-21-11-10-18-16(17(21)8-9-19(21)24)7-6-14-12-15(23)13-20(22(14,18)2)25-26(3,4)5/h12,15-20,23-24H,6-11,13H2,1-5H3/t15?,16?,17?,18?,19-,20-,21-,22-/m0/s1', 'inchi_key': 'RNOPMFBADSIDRA-XLVMOJGQSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:43:46.092736', 'metadata_modified': '2025-03-22T14:43:46.092742', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeii-050b_full_nabh4_3oh_delta4_tmsc1_17oh_01_08_2024_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL date: 2024-01-08T22:51:30.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/1 phc0: -93.72746 phc1: 49.68005 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1491 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 24703.557312252968 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T04:42:32.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/2 phc0: -16.55622 phc1: -163.1828 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.991059602238 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1494 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 512 pulseSequence: udeft spectralWidth: 283.964238408952 numberOfPoints: 5 relaxationTime: 4 acquisitionTime: 0.00005599999999999992 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2024-01-09T04:49:15.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/3 phc0: -5.940369 phc1: 234.8051 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.991059602238 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9910888671875 temperature: 298.1491 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 283.964238408952 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00005599999999999992 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T05:02:05.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/4 phc0: -75.8622 phc1: 348.861 type: NMR Spectrum DECIM: 560 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 70.99247931054725 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9910888671875 temperature: 298.1513 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 256 pulseSequence: deptsp135 spectralWidth: 283.969917242189 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00005600000000000007 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 15625 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2024-01-09T05:09:34.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1504 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 24703.557312252968 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2024-01-09T05:20:13.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1494 spectrumSize: 4096,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 24703.557312252968 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2024-01-09T05:21:47.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1497 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00030800000000000006 frequencyOffset: 3000.779999979386,3000.779999979386 originFrequency: 500.13300078,500.13300078 pulseStrength90: 24703.557312252968 experimentNumber: 7 acquisitionScheme: notPhaseSensitive linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 4,4 date: 2024-01-09T06:05:53.000Z isFt: true name: AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL/8 phc0: -44.21659,267.9648 phc1: 30.88338,-180 type: NMR Spectrum DECIM: 4000 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.33245122942065 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: noesy groupDelay: 67.9842834472656 temperature: 298.1491 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: noesygpphpp spectralWidth: 9.99735368826195,9.99735368826195 numberOfPoints: 4 relaxationTime: 2 acquisitionTime: 0.00030000000000000003 frequencyOffset: 2350.610999997116,2350.610999997116 originFrequency: 500.132350611,500.132350611 pulseStrength90: 24703.557312252968 experimentNumber: 8 acquisitionScheme: States-TPPI linearPredictionBin: 0,0 lpNumberOfCoefficients: 0,0 windowMultiplicationMode: 4,4', 'num_resources': 1, 'num_tags': 1, 'organization': {'id': '14e443f8-70e7-497d-9785-3727d79901ab', 'name': 'nmrxiv', 'title': 'nmrXiv', 'type': 'repository', 'description': 'The Open, FAIR and Consensus-Driven NMR spectroscopy data repository and analysis platform.', 'image_url': 'nmrXiv_logo.svg', 'created': '2024-04-22T15:05:05.930653', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '14e443f8-70e7-497d-9785-3727d79901ab', 'private': False, 'related_molecule': '[]', 'smiles': 'C[C@]12CCC3C(CCC4=CC(O)C[C@H](O[Si](C)(C)C)[C@@]43C)C1CC[C@@H]2O', 'state': 'active', 'title': 'AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL.dept', 'type': 'dataset', 'url': 'https://nmrxiv.org/D4234', 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2025-03-22T14:43:46.094925', 'format': 'HTML', 'hash': '', 'id': 'ddb8624c-0809-45f4-bf11-08a8552e5d2f', 'last_modified': None, 'metadata_modified': '2025-03-22T14:43:46.088513', 'mimetype': None, 'mimetype_inner': None, 'name': 'AEII-050B_FULL_NaBH4_3OH_delta4_TMSC1_17OH_01_08_2024_FULL.dept', 'package_id': 'nmrxiv-d4234', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://nmrxiv.org/D4234', 'url_type': None}], 'tags': [{'display_name': 'distortionless-enhancement-with-polarization-transfer', 'id': 'ee491bbd-7ccd-4820-8a4a-a1517e7b41d0', 'name': 'distortionless-enhancement-with-polarization-transfer', 'state': 'active', 'vocabulary_id': None}], 'variableMeasured': [{'variableMeasured_name': 'NMR solvent', 'variableMeasured_propertyID': 'NMR:1000330', 'variableMeasured_value': 'CDCl3'}, {'variableMeasured_name': 'acquisition nucleus', 'variableMeasured_propertyID': 'NMR:1400083', 'variableMeasured_value': "['13C']"}, {'variableMeasured_name': 'NMR spectrum by dimensionality', 'variableMeasured_propertyID': 'NMR:1000117', 'variableMeasured_value': '1'}, {'variableMeasured_name': 'NMR probe', 'variableMeasured_propertyID': 'OBI:0000516', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/OBI_0000516', 'variableMeasured_value': 'Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z)'}, {'variableMeasured_name': 'Temperature', 'variableMeasured_propertyID': 'NCIT:C25206', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C25206', 'variableMeasured_value': '298.1513'}, {'variableMeasured_name': 'irradiation frequency', 'variableMeasured_propertyID': 'NMR:1400026', 'variableMeasured_value': '125.757788526'}, {'variableMeasured_name': 'magnetic field strength', 'variableMeasured_propertyID': 'MR:1400253', 'variableMeasured_value': '11.743848641495527'}, {'variableMeasured_name': 'number of scans', 'variableMeasured_propertyID': 'NMR:1400087', 'variableMeasured_value': '256'}, {'variableMeasured_name': 'nuclear magnetic resonance pulse sequence', 'variableMeasured_propertyID': 'CHMO:0001841', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/CHMO_0001841', 'variableMeasured_value': 'deptsp135'}, {'variableMeasured_name': 'Spectral Width', 'variableMeasured_propertyID': 'NCIT:C156496', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/NCIT_C156496', 'variableMeasured_value': '283.969917242189'}, {'variableMeasured_name': 'number of data points', 'variableMeasured_propertyID': 'NMR:1000176', 'variableMeasured_value': '5'}, {'variableMeasured_name': 'relaxation time measurement', 'variableMeasured_propertyID': 'FIX:0000202', 'variableMeasured_tsurl': 'http://purl.obolibrary.org/obo/FIX_0000202', 'variableMeasured_value': '2'}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': [], 'extras': [{'key': 'harvest_object_id', 'value': '4dda5218-c969-42e4-9001-771aabff7928'}, {'key': 'harvest_source_id', 'value': '289ee33f-3b9e-4677-b96f-56659c421105'}, {'key': 'harvest_source_title', 'value': 'nmrXiv Harvester'}]}, {'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'doi': '10.57992/nmrxiv.p98.s861.d4260', 'id': 'nmrxiv-d4260', 'inchi': 'InChI=1S/C24H36O4/c1-22(2,3)21(27)28-15-12-14-6-7-16-17-8-9-19(25)23(17,4)11-10-18(16)24(14,5)20(26)13-15/h14-18H,6-13H2,1-5H3/t14?,15-,16?,17?,18?,23+,24+/m1/s1', 'inchi_key': 'LRBBBGJCZNNDMR-LMVFSPIVSA-N', 'isopen': False, 'language': 'english', 'license_id': 'CC0 1.0 Universal ', 'license_title': ' CC0 1.0 Legal Code ', 'license_url': 'https://creativecommons.org/publicdomain/zero/1.0/legalcode', 'maintainer_email': None, 'measurement_technique': 'distortionless enhancement with polarization transfer', 'measurement_technique_iri': 'CHMO:0000596', 'metadata_created': '2025-03-22T14:43:24.189176', 'metadata_modified': '2025-03-22T14:43:24.189181', 'metadata_published': '2025-03-20 23:01:25', 'name': 'aeii-024b_monoester_3opiv_c4_epoxy_c1_17_diketone_pcc_11-22-2023_full-dept', 'notes': 'This dataset contains NMR spectra obtained for the sample -AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL date: 2023-11-22T23:16:23.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/1 phc0: -85.35435 phc1: 48.18853 type: NMR Spectrum DECIM: 2000 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H reverse: false solvent: CDCl3 dimension: 1 increment: 4.998669471131275 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 67.9862518310547 temperature: 298.1491 spectrumSize: 65536 baseFrequency: 500.13 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: zg30 spectralWidth: 19.9946778845251 numberOfPoints: 5 relaxationTime: 1 acquisitionTime: 0.00020000000000017524 frequencyOffset: 3088.3019999805583 originFrequency: 500.133088302 pulseStrength90: 24703.557312252968 experimentNumber: 1 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-11-23T08:50:42.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/2 phc0: -66.53648 phc1: -48.86498 type: NMR Spectrum DECIM: 634.666666666667 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 25.0556680949075 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: 1d groupDelay: 76 temperature: 298.1504 spectrumSize: 131072 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 800 pulseSequence: udeft spectralWidth: 250.556680949075 numberOfPoints: 11 relaxationTime: 4 acquisitionTime: 0.0001586666666666666 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 2 linearPredictionBin: 262144 lpNumberOfCoefficients: 4096 windowMultiplicationMode: 1 date: 2023-11-23T08:57:50.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/3 phc0: 33.71075 phc1: 208.8626 type: NMR Spectrum DECIM: 672 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 59.159216335354 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9838256835938 temperature: 298.1488 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 128 pulseSequence: deptsp90 spectralWidth: 236.636865341416 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00006719999999982307 frequencyOffset: 12575.779000002285 originFrequency: 125.770364305 pulseStrength90: 15625 experimentNumber: 3 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-11-23T09:00:02.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/4 phc0: -6.141327 phc1: 232.9605 type: NMR Spectrum DECIM: 992 aqMod: 3 isFid: false tdOff: 0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 13C reverse: false solvent: CDCl3 dimension: 1 increment: 40.07639961064025 isComplex: true probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: dept groupDelay: 67.9840087890625 temperature: 298.1516 spectrumSize: 32768 baseFrequency: 125.757788526 fieldStrength: 11.743848641495527 numberOfScans: 32 pulseSequence: deptsp135 spectralWidth: 160.305598442561 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.00009920000000037773 frequencyOffset: 10060.621999997466 originFrequency: 125.767849148 pulseStrength90: 15625 experimentNumber: 4 linearPredictionBin: 0 lpNumberOfCoefficients: 0 windowMultiplicationMode: 1 date: 2023-11-23T09:07:31.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/5 phc0: -159.3368,3.253899 phc1: -12.14621,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 21 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.2458940546305 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hsqc groupDelay: 76 temperature: 298.1479 spectrumSize: 2048,2048 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hsqcedetgpsisp2.3 spectralWidth: 12.983576218522,164.962602395549 numberOfPoints: 5 relaxationTime: 1.5 acquisitionTime: 0.00030800000000000033 frequencyOffset: 2350.610999997116,9431.835000000887 originFrequency: 500.132350611,125.767220361 pulseStrength90: 24703.557312252968 experimentNumber: 5 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,60 windowMultiplicationMode: 4,4 date: 2023-11-23T09:18:11.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/6 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,13C reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24589145792955 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: hmbc groupDelay: 67.985595703125 temperature: 298.1494 spectrumSize: 2048,1024 baseFrequency: 500.13,125.757788526 fieldStrength: 11.746350827011339 numberOfScans: 8 pulseSequence: hmbcetgpl3nd spectralWidth: 12.9835658317182,239.487911911164 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 0.0003079999999999992 frequencyOffset: 2750.714999990578,12575.779000002285 originFrequency: 500.132750715,125.770364305 pulseStrength90: 24703.557312252968 experimentNumber: 6 acquisitionScheme: Echo-antiecho linearPredictionBin: 0,256 lpNumberOfCoefficients: 0,32 windowMultiplicationMode: 3,4 date: 2023-11-23T09:19:50.000Z isFt: true name: AEII-024B_monoester_3OPiv_C4_epoxy_C1_17_diketone_PCC_11.22.2023_FULL/7 phc0: 0,0 phc1: 0,0 type: NMR Spectrum DECIM: 3080 aqMod: 3 isFid: false tdOff: 0,0 title: Parameter file, TopSpin 3.6.2 DSPFVS: 20 nucleus: 1H,1H reverse: false,false solvent: CDCl3 dimension: 2 increment: 3.24588983499355 isComplex: false probeName: Z149001_0004 (CPP BBO 500S1 BB-H&F-05 Z) experiment: cosy groupDelay: 67.985595703125 temperature: 298.1503 spectrumSize: 1024,1024 baseFrequency: 500.13,500.13 fieldStrength: 11.746350827011339 numberOfScans: 1 pulseSequence: cosygpppqf spectralWidth: 12.9835593399742,12.9835593399742 numberOfPoints: 5 relaxationTime: 2 acquisitionTime: 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', 'page': Page:
Collection type: <class 'list'>
(Current) page: 1
First item: 1
Last item: 14
First page: 1
Last page: 1
Previous page: None
Next page: None
Items per page: 20
Number of items: 14
Number of pages: 1
} |
