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Various aspects such as concentration dependence, substrate size and temperature dependence have been discussed.<br><br> \n\nIn the attached data you will find all NMR spectra of the performed reactions as well as the sorption measurements, ICP analyses, elemental analyses, Maldi-TOF and SEM pictures. All data are sorted according to the labeling in the paper.<br><br>\n\nAll primary data files and processed data of the journal article from the Buchmeiser group and links to related data sets from other groups.', 'num_resources': 1, 'num_tags': 5, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Olefin Metathesis in Confined Geometries: A Biomimetic Approach toward Selective Macrocyclization Data Buchmeiser', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Ziegler, Felix'}, {'key': 'creator', 'value': 'Ziegler, Felix'}, {'key': 'date', 'value': '2020-12-23T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-832'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:03'}, {'key': 'relation', 'value': 'Felix Ziegler, Johannes Teske, Iris Elser, Michael Dyballa, Wolfgang Frey, Hamzeh Kraus, Niels Hansen, Julia Rybka, Ulrich Tallarek, Michael R. Buchmeiser CCDC 1942469: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23699y">10.5517/ccdc.csd.cc23699y</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '8a7e8a72-295f-4400-83e5-15abf928ef90'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:14:23.489548', 'format': 'HTML', 'hash': '', 'id': 'ddab5dd7-345f-462e-bc1c-096ad5087484', 'last_modified': None, 'metadata_modified': '2023-05-08T19:14:23.472814', 'mimetype': None, 'mimetype_inner': None, 'name': 'Olefin Metathesis in Confined Geometries: A Biomimetic Approach toward Selective Macrocyclization Data Buchmeiser', 'package_id': 'doi-10-18419-darus-832', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 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'metadata_modified': '2023-05-08T19:14:14.269390', 'name': 'doi-10-18419-darus-3348', 'notes': 'All primary data files of measurements and processed data of the journal article "Comparative study of lattice parameter and pore size of ordered mesoporous silica materials using physisorption, SAXS measurements and transmission electron microscopy", are deposited. File types which are not easily readable have been converted to other formats, i.e. TIF and TXT, and have been deposited additionally. PDH files may be opened with the same applications as TXT files. <p> The dataset contains the following data: nitrogen physisorption measurements, small-angle X-ray scattering curves, transmission electron micrographs. The data is named according to the sample name. A short description of the samples is given in the following:\n<p>\n<p>\n<b>OMS_TLCT:</b> Ordered mesoporous silica material synthesized via true liquid crystal templating with hexadecylethyldimethylammonium chloride as surfactant\n<p>\n<p>\n<b>MCM-41:</b> Ordered mesoporous silica material synthesized via a cooperative self-assembly process with hexadecyltrimethylammonium chloride as surfactant\n<p>\n<p>\n<b>SBA-15:</b> Ordered mesoporous silica material synthesized via a cooperative self-assembly process with the poloxamer P123 as surfactant\n<p>\n<p>\n<b>SBA-15_sa:</b> Ordered mesoporous silica material synthesized via a cooperative self-assembly process with the poloxamer P123 as surfactant and n-decane as swelling agent', 'num_resources': 1, 'num_tags': 7, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data for: "Comparative study of lattice parameter and pore size of ordered mesoporous silica materials using physisorption, SAXS measurements and transmission electron microscopy"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Bruckner, Johanna R.'}, {'key': 'creator', 'value': 'Beurer, Ann-Katrin'}, {'key': 'date', 'value': '2023-04-26T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-3348'}, {'key': 'metadata_modified', 'value': '2023-04-27T00:00:05'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '4ba7e0d2-66af-42a1-841a-08309a0fe916'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:14:14.270952', 'format': 'HTML', 'hash': '', 'id': 'b1f5d1e6-e81e-4fdd-ac16-40f6a751230f', 'last_modified': None, 'metadata_modified': '2023-05-08T19:14:14.258902', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data for: "Comparative study of lattice parameter and pore size of ordered mesoporous silica materials using physisorption, SAXS measurements and transmission electron microscopy"', 'package_id': 'doi-10-18419-darus-3348', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-3348', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'mcm-41', 'id': 'dc3b63ce-cf26-4561-acb4-6d9af046e7a0', 'name': 'mcm-41', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'mesoporous-silica', 'id': '2383957f-1ab0-4a4c-be9c-8b415ebe1f72', 'name': 'mesoporous-silica', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'physisorption', 'id': 'bcd4f7fa-8729-4acc-91a3-553a51ecf3ce', 'name': 'physisorption', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'small-angle-x-ray-scattering-saxs', 'id': '1e279138-e340-4462-a248-79f0591d35cb', 'name': 'small-angle-x-ray-scattering-saxs', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'transmission-electron-microscopy-tem', 'id': '15a03b4e-0a79-4fb8-b898-24d033f16fee', 'name': 'transmission-electron-microscopy-tem', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Rieg, Carolin, Dyballa, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-3306', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:14:11.349686', 'metadata_modified': '2023-05-08T19:14:11.349691', 'name': 'doi-10-18419-darus-3306', 'notes': 'Solid-state NMR data of the journal article mentioned under related publications from the Dyballa group can be found here. Data from collaborating groups (A2, A4, B3, C4) can be found in separate data sets.', 'num_resources': 1, 'num_tags': 3, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data of Dyballa group for: "Determination of Accessibility and Spatial Distribution of Chiral Rh Diene Complexes Immobilized on SBA-15 via Phosphine‐based NMR Probe Molecules"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Rieg, Carolin'}, {'key': 'creator', 'value': 'Rieg, Carolin'}, {'key': 'date', 'value': '2023-01-19T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-3306'}, {'key': 'metadata_modified', 'value': '2023-01-20T01:00:05'}, {'key': 'relation', 'value': 'Structure [RhCl(L1)(P(Ad)2(n-Bu))]: Carolin Rieg, Manuel Kirchhof, Katrin Gugeler, Ann-Katrin Beurer, Lukas Stein, Klaus Dirnberger, Wolfgang Frey, Johanna R. Bruckner, Yvonne Traa, Johannes Kästner, Sabine Ludwigs, Sabine Laschat, Michael Dyballa, CCDC 2195463: Experimental Crystal Structure Determination, 2022, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc2cpkd1">10.5517/ccdc.csd.cc2cpkd1</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': 'fb72fd3e-213a-496c-b0ed-08d2b100a312'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:14:11.357078', 'format': 'HTML', 'hash': '', 'id': 'cf366ce8-545d-4999-9272-0b6e556d8b79', 'last_modified': None, 'metadata_modified': '2023-05-08T19:14:11.342427', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data of Dyballa group for: "Determination of Accessibility and Spatial Distribution of Chiral Rh Diene Complexes Immobilized on SBA-15 via Phosphine‐based NMR Probe Molecules"', 'package_id': 'doi-10-18419-darus-3306', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-3306', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'heterogeneous-catalysis', 'id': '86b5272a-37ca-43c8-b338-18e1995d1ff5', 'name': 'heterogeneous-catalysis', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Kirchhof, Manuel', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-3272', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:14:08.707491', 'metadata_modified': '2023-05-08T19:14:08.707497', 'name': 'doi-10-18419-darus-3272', 'notes': 'In this dataset HPLC (high performance liquid chromatography) chromatograms of the products of the rhodium-catalyzed 1,2-addition and NMR spectra of all prepared catalysts and catalysis products (NMR) are included. The described 1,2-addition product is an N-tosyl amide which was formed from the reaction of triphenylboroxine with an N-tosyl imine. The catalysts are the chiral Rh norbornadiene phosphine complexes [RhCl(L1)(P(Ad)2(n-Bu))] and [RhCl(L1)(PPh3)]. Furthermore, the NMR data of phosphine complexation experiments is deposited. This data was collected to screen for suitable phosphines for the later quantification of accessible Rh diene complexes on SBA-15 via solid state NMR. Crystallographic data was published in Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC) as stated under related datasets. In this dataset additional data from the crystal structure of [RhCl(L1)(P(Ad)2(n-Bu))] is included (plotted structure, CIF file, PDB file, RES file and a DAT file with tables listing all the significant measuring parameters, bond angles, bond distances and atom coordinates).', 'num_resources': 1, 'num_tags': 9, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Data of B3 group for: "Determination of Accessibility and Spatial Distribution of Chiral Rh Diene Complexes Immobilized on SBA-15 via Phosphine‑based NMR Probe Molecules"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Kirchhof, Manuel'}, {'key': 'creator', 'value': 'Kirchhof, Manuel'}, {'key': 'date', 'value': '2022-12-13T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-3272'}, {'key': 'metadata_modified', 'value': '2022-12-14T01:00:05'}, {'key': 'relation', 'value': 'Structure [RhCl(L1)(P(Ad)2(n-Bu))]: Carolin Rieg, Manuel Kirchhof, Katrin Gugeler, Ann-Katrin Beurer, Lukas Stein, Klaus Dirnberger, Wolfgang Frey, Johanna R. Bruckner, Yvonne Traa, Johannes Kästner, Sabine Ludwigs, Sabine Laschat, Michael Dyballa, CCDC 2195463: Experimental Crystal Structure Determination, 2022, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc2cpkd1">10.5517/ccdc.csd.cc2cpkd1</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '2dad7840-1c40-4a26-88ec-033c72570e11'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:14:08.709237', 'format': 'HTML', 'hash': '', 'id': '74c7706a-4b82-4873-bef1-8d96e00bee06', 'last_modified': None, 'metadata_modified': '2023-05-08T19:14:08.693838', 'mimetype': None, 'mimetype_inner': None, 'name': 'Data of B3 group for: "Determination of Accessibility and Spatial Distribution of Chiral Rh Diene Complexes Immobilized on SBA-15 via Phosphine‑based NMR Probe Molecules"', 'package_id': 'doi-10-18419-darus-3272', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-3272', 'url_type': None}], 'tags': [{'display_name': 'asymmetric-catalysis', 'id': 'fed94913-f045-4f9f-8e39-65b81c869cea', 'name': 'asymmetric-catalysis', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'confinement', 'id': '6cb7505c-f92e-435f-a1dc-e7542d4a061a', 'name': 'confinement', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'diene-ligands', 'id': 'ad013382-9245-4667-bdc1-a436b823be13', 'name': 'diene-ligands', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'nmr-spectroscopy', 'id': 'f9a256af-c7a9-4bb2-b692-84675d928483', 'name': 'nmr-spectroscopy', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'phosphine', 'id': '8f62a337-0e73-43de-b0e5-dd46a28536fe', 'name': 'phosphine', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'probe-molecules', 'id': '835f5a10-d5c6-4918-9c3c-0ccbc6acbccf', 'name': 'probe-molecules', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'rhodium-catalysis', 'id': 'dee4bd4e-ccde-4323-b35b-d072bf744e0c', 'name': 'rhodium-catalysis', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Musso, Janis, Silva, Jordan De Jesus, Benedikter, Mathis, Groos, Jonas, Frey, Wolfgang, Coperet, Christophe, Buchmeiser, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-3013', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:57.602425', 'metadata_modified': '2023-05-08T19:13:57.602431', 'name': 'doi-10-18419-darus-3013', 'notes': 'All primary data files of measurements and processed data of the journal article mentioned under related publications from the Buchmeiser group and the Copéret gropup can be found here. <br/>\nThe data consist of:<br/>\n*Processed (mestrenova) and unprocessed (fid-files) NMR spectra of molecular compunds<br/>\n*FT-IR spectra<br/>\n*Catalysis data (excel sheets)<br/>\n*Data for calculating the catalyst loading on the silica<br/>\n*Solid state NMR spectra of the immobilized catalyst', 'num_resources': 1, 'num_tags': 3, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data for: "Cationic molybdenum oxo alkylidenes stabilized by N-heterocyclic carbenes: from molecular systems to efficient supported metathesis catalysts"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Musso, Janis'}, {'key': 'creator', 'value': 'Musso, Janis'}, {'key': 'date', 'value': '2022-07-13T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-3013'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:05'}, {'key': 'relation', 'value': 'Crystal data for Mo-2: Janis V. Musso, Jordan De Jesus Silva, Mathis J. Benedikter, Jonas Groos, Wolfgang Frey, Christophe Copéret, Michael R. Buchmeiser CCDC 2151036: Experimental Crystal Structure Determination, 2022, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc2b6b85">10.5517/ccdc.csd.cc2b6b85</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '08bb39db-27c7-414b-8424-b46a0e6134e1'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:57.603945', 'format': 'HTML', 'hash': '', 'id': 'd4c3e251-f15e-4ecd-b75e-59362fe47dde', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:57.595911', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data for: "Cationic molybdenum oxo alkylidenes stabilized by N-heterocyclic carbenes: from molecular systems to efficient supported metathesis catalysts"', 'package_id': 'doi-10-18419-darus-3013', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-3013', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'metathesis', 'id': '62ec03a6-9504-48c7-9261-c43ce49d375b', 'name': 'metathesis', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Rieg, Carolin, Dittmann, Daniel, Li, Zheng, Kurtz, Alan, Kaya, Elif, Peters, Stefan, Kunkel, Benny, Parlinska-Wojtan, Magdalena, Wohlrab, Sebastian, Abdel-Mageed, Ali, Dyballa, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2992', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:55.990478', 'metadata_modified': '2023-05-08T19:13:55.990483', 'name': 'doi-10-18419-darus-2992', 'notes': 'Primary data files of measurements and processed data of the journal article mentioned under related publications from Dyballa group can be found here. This comprises <a href="http://purl.obolibrary.org/obo/CHMO_0000615">MAS-NMR</a>, <a href="http://purl.obolibrary.org/obo/CHMO_0000267">ICP-OES</a>, N2-<a href="http://purl.obolibrary.org/obo/REX_0000207">Physisorption</a> (Brunauer-Emmett-Teller method; BET), <a href="http://purl.obolibrary.org/obo/CHMO_0000156">XRD</a>, and <a href="http://purl.obolibrary.org/obo/CHMO_0000086">STEM</a> data. The STEM images are stored in the folder "STEM".', 'num_resources': 1, 'num_tags': 3, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Publication data of Dyballa group for: "Introducing a Novel Method for Probing Accessibility, Local Environment and Spatial Distribution of Oxidative Sites on Solid Catalysts using Trimethylphosphine"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Rieg, Carolin'}, {'key': 'creator', 'value': 'Rieg, Carolin'}, {'key': 'date', 'value': '2022-08-27T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-2992'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:05'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': 'ff24b385-7050-4f2f-bc67-afb8c082cddd'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:55.997242', 'format': 'HTML', 'hash': '', 'id': '4ae7bddd-e32b-41bd-bc6b-f07c12da502a', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:55.984633', 'mimetype': None, 'mimetype_inner': None, 'name': 'Publication data of Dyballa group for: "Introducing a Novel Method for Probing Accessibility, Local Environment and Spatial Distribution of Oxidative Sites on Solid Catalysts using Trimethylphosphine"', 'package_id': 'doi-10-18419-darus-2992', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-2992', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'zeolite', 'id': '68d28f7a-a8a9-4087-ae66-90ae9992d413', 'name': 'zeolite', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Panyam, Pradeep Kumar Reddy, Atwi, Boshra, Ziegler, Felix, Frey, Wolfgang, Nowakowski, Michal, Bauer, Matthias, Buchmeiser, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2473', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:44.738343', 'metadata_modified': '2023-05-08T19:13:44.738347', 'name': 'doi-10-18419-darus-2473', 'notes': '<p>Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes. Selected catalysts were immobilized within the mesopores of SBA-15. The confinement effects either provided by the ligands or the mesoporous support have been studied and allow for hydrosilylation with β(Z)-selectivity of up to 100\u2009% with both Rh(I) and Rh(III) complexes.</p>\n\n<p>All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here.</p>\n\nThe following dataset contains the following data types: NMR Spectra and HRMS data. The Crystal data (see related datasets) is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).', 'num_resources': 1, 'num_tags': 4, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Panyam, Pradeep Kumar Reddy'}, {'key': 'creator', 'value': 'Panyam, Pradeep Kumar Reddy'}, {'key': 'date', 'value': '2022-02-07T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-2473'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:05'}, {'key': 'relation', 'value': 'Crystal data of Rh3 <br/>\nPradeep K. R. Panyam, Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michal Nowakowski, Matthias Bauer, Michael R. Buchmeiser CCDC 2082933: Experimental Crystal Structure Determination, 2021, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc27xgd1">10.5517/ccdc.csd.cc27xgd1</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '2d60bc30-238e-48d4-875e-29885b92bbd2'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:44.742111', 'format': 'HTML', 'hash': '', 'id': '99e9e290-ab6f-4724-a0a5-e97a5d1df607', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:44.730919', 'mimetype': None, 'mimetype_inner': None, 'name': 'Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes', 'package_id': 'doi-10-18419-darus-2473', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-2473', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'n-heterocyclic-carbene', 'id': 'a8ad4bb7-9e2f-4332-acdb-e74e337cddb0', 'name': 'n-heterocyclic-carbene', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'nhc', 'id': '552610fb-34f1-4397-a8ec-9aa48eb493ca', 'name': 'nhc', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Vogler, Charlotte, Naumann, Stefan, Bruckner, Johanna R.', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2374', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:42.326210', 'metadata_modified': '2023-05-08T19:13:42.326215', 'name': 'doi-10-18419-darus-2374', 'notes': 'All primary data files of measurements and processed data (GPC, 1H-NMR, deconvoluted SAXS, nitrogen physisorption) of the associated journal article can be found here.<br>\nThe data is structured according to sample type, i.e. polymer or ordered mesoporous silica, experiment type and the specific sample investigated. It contains the following data types: PDF, TXT, PDH as well as some additional raw data formats, which are duplicated in one of the other, easily readable data formats. PDH files can be opened with a text editor or imported into plotting software.', 'num_resources': 1, 'num_tags': 7, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data of Bruckner group for: "Predictive design of ordered mesoporous silica with well-defined, ultra-large mesopores"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Bruckner, Johanna R.'}, {'key': 'creator', 'value': 'Vogler, Charlotte'}, {'key': 'date', 'value': '2022-07-15T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-2374'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:05'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '25a715f8-24c7-4ac3-bc99-403413bd3376'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:42.338156', 'format': 'HTML', 'hash': '', 'id': 'f3e64a08-f986-41ee-bcb9-879983e5d636', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:42.315986', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data of Bruckner group for: "Predictive design of ordered mesoporous silica with well-defined, ultra-large mesopores"', 'package_id': 'doi-10-18419-darus-2374', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-2374', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'ordered-mesoporous-silica', 'id': 'c7360b58-a44f-4cda-93d8-20c61a28aa4f', 'name': 'ordered-mesoporous-silica', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'polyether', 'id': 'eecc0bc4-f03b-4ef1-9cfa-72b3ca9aee07', 'name': 'polyether', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'pore-size-control', 'id': 'c1a4d9e9-575d-4b91-870a-c8d62623c3c0', 'name': 'pore-size-control', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'true-liquid-crystal-templating', 'id': '3cd14a99-3eda-4830-9a42-962a8093e2cb', 'name': 'true-liquid-crystal-templating', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'ultra-large-mesopores', 'id': '0e70d1b8-4ffc-4155-b2e4-66e837e84f92', 'name': 'ultra-large-mesopores', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Beurer, Ann-Katrin', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2268', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:40.248256', 'metadata_modified': '2023-05-08T19:13:40.248262', 'name': 'doi-10-18419-darus-2268', 'notes': 'The manuscript describes the influence of the template removal method on the mechanical stability of SBA-15. First, the mechanical stability of calcined SBA-15 was investigated similar to known procedures from literature. The results of the literature were reproduced and confirmed. The main part of the manuscript deals with the mechanical stability of SBA-15, whose pores were opened in different ways - calcination, Soxhlet extraction with ethanol, and Soxhlet extraction with ethanol combined with a thermal treatment in nitrogen.<br>\nThe data used for the manuscript are sorted by the respective characterization method. The data are named according to the sample name (for nomenclature see Notes). The data of the SAXS measurement are sorted by the measurement date. All data are raw data that can be processed with the corresponding software.', 'num_resources': 1, 'num_tags': 6, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data for: "Influence of the Template Removal Method on the Mechanical Stability of SBA-15"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Beurer, Ann-Katrin'}, {'key': 'creator', 'value': 'Beurer, Ann-Katrin'}, {'key': 'date', 'value': '2022-01-28T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-2268'}, {'key': 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{'author': 'Musso, Janis, Benedikter, Mathis, Gebel, Paul, Gramm, Vincent, Schowner, Roman, Buchmeiser, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2222', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:36.623173', 'metadata_modified': '2023-05-08T19:13:36.623178', 'name': 'doi-10-18419-darus-2222', 'notes': '<p>All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here.</p> \n\n<p>The data is structured according to figures and schemes in the research article and contains the following data types: mestrenova, excel, fid.</p>\n\n<p>Further experimental for reproduction of experiemnts can be found in the supporting information.</p>', 'num_resources': 1, 'num_tags': 5, 'organization': {'id': 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'1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-2210', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:36.350615', 'metadata_modified': '2023-05-08T19:13:36.350619', 'name': 'doi-10-18419-darus-2210', 'notes': 'In this dataset HPLC (high performance liquid chromatography) chromatograms of the products of the rhodium-catalyzed 1,2-addition and NMR spectra of all prepared ligands, catalysts and catalysis products (NMR) are included. Furthermore, the NMR data of temperature and solvent dependent kinetics in dioxane and in microemulsions (Kinetiken) are listed.\n\nCrystallographic data was published in Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC) as stated under related datasets.', 'num_resources': 1, 'num_tags': 12, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data of B3 group for: "Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Kirchhof, Manuel'}, {'key': 'creator', 'value': 'Kirchhof, Manuel'}, {'key': 'date', 'value': '2022-02-21T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-2210'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:04'}, {'key': 'relation', 'value': 'Structure L2-H2: CCDC 2099410 doi: <a href="https://doi.org/10.5517/ccdc.csd.cc28glx8">10.5517/ccdc.csd.cc28glx8</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '61aa94ed-7911-4080-9a92-d96e7e355822'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:36.352619', 'format': 'HTML', 'hash': '', 'id': 'a90f1076-e41f-4e3d-83ee-47896fc4e6bd', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:36.336668', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data of B3 group for: "Interplay of Polarity and Confinement in Asymmetric Catalysis with Chiral Rh Diene Complexes in Microemulsions"', 'package_id': 'doi-10-18419-darus-2210', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-2210', 'url_type': None}], 'tags': [{'display_name': 'amphiphilic-film', 'id': '06087f4e-9f63-4115-acc1-5313225a116d', 'name': 'amphiphilic-film', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'analytical-data', 'id': '408c47d0-d908-4e94-a4d5-3108ad450cc3', 'name': 'analytical-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'anion-exchange', 'id': 'e627d589-28d6-4c0b-9872-7c0d50a65bbf', 'name': 'anion-exchange', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'asymmetric-catalysis', 'id': 'fed94913-f045-4f9f-8e39-65b81c869cea', 'name': 'asymmetric-catalysis', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'c-c-coupling', 'id': '4ce8fb42-e16e-42ba-9ec6-7d8369c8ac0e', 'name': 'c-c-coupling', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'diene-ligands', 'id': 'ad013382-9245-4667-bdc1-a436b823be13', 'name': 'diene-ligands', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'kinetics', 'id': '29ab8754-7f33-4dd5-8ced-8ad31a218874', 'name': 'kinetics', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'liquid-confinement', 'id': '71f59e3a-ed1c-4907-b94f-a5e0c8349175', 'name': 'liquid-confinement', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'microemulsion', 'id': '9834d763-e1c2-4202-9c1f-34399b19128a', 'name': 'microemulsion', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'rhodium-catalysis', 'id': 'dee4bd4e-ccde-4323-b35b-d072bf744e0c', 'name': 'rhodium-catalysis', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Piotrowski, Joseph, Huisman, Johan Alexander', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1861', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:18.967545', 'metadata_modified': '2023-05-08T19:13:18.967552', 'name': 'doi-10-18419-darus-1861', 'notes': 'The dataset contains data from evaporation of magnesium sulfate solution with an initial concentration of 0.96 mol/L, 0.64 mol/L, and 0.32 mol/L from F32 quartz sand. Additionally, pressure measurement of the separated and dried crusts from 40%, 30%, and 20(25)% saturation inside of the sample are provided using dry nitrogen gas (dynamic viscosity 0.0176 mPas at 20°C, flow rates 0 mL/min, 100 mL/min, 200 mL/min, 300 mL/min). A linear regression on the measured pressure difference was performed with MATLAB and the corresponding intrinsic crust permeability was calculated using the obtained pressure difference and the crust thickness that was determined from XRCT data for each crust (see related data sets).<br/> \nEach excel file has six sheets: \n<ol>\n<li>Sample properties (i.e. dimensions, effective properties, weight,...) </li>\n<li>Evaporation (i.e. mass loss of each sample determined over time, temperature, relative humidity) </li>\n<li>Mass loss (calculated for each sample from evaporation data, final saturation/water content) </li>\n<li>Evaporation rate (calculated for each sample from mass loss, time) </li>\n<li>Water balance (sample properties after evaporation, properties of separated crust, water content of crust and removed sand)</li>\n<li>Plots (plots of cumulative mass loss, evaporation rate, and ambient conditions). </li>\n</ol>\nThe sand used is F32 quartz sand from Quarzwerke Frechen with a mean grain size of 240 µm (see related publication for more details). The sample properties and the evaporation data are further provided as .CSV files, which represent the first and second sheet of the corresponding .XLSX file. The pressure measurements are provided as .CSV files for each crust.', 'num_resources': 1, 'num_tags': 9, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Sample Properties, Evaporation Data, and Pressure Measurements of MgSO4 Crusts on F32 Quartz Sand From 0.96 mol/L, 0.64 mol/L, and 0.32 mol/L Initial Concentration', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Piotrowski, Joseph'}, {'key': 'creator', 'value': 'Piotrowski, Joseph'}, {'key': 'date', 'value': '2021-09-02T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-1861'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:04'}, {'key': 'relation', 'value': 'Ruf, M, Lee, D., Piotrowski, J., Huisman, J.A., Steeb, H.(2021). micro-XRCT and segmented data sets of subflorescent salt crusts from evaporation of MgSO4 solution with 0.96 mol/L initial concentration. DaRUS. <a href="https://doi.org/10.18419/darus-2003">https://doi.org/10.18419/darus-2003</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': 'f42c9262-a21a-4376-b99c-b987cae62c9e'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:18.982363', 'format': 'HTML', 'hash': '', 'id': 'f4f9f1cd-bc67-49ee-b1a4-a3bfa0b2eddf', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:18.955866', 'mimetype': None, 'mimetype_inner': None, 'name': 'Sample Properties, Evaporation Data, and Pressure Measurements of MgSO4 Crusts on F32 Quartz Sand From 0.96 mol/L, 0.64 mol/L, and 0.32 mol/L Initial Concentration', 'package_id': 'doi-10-18419-darus-1861', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-1861', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'crust-permeability', 'id': 'fac4cdba-c5fa-47a3-925a-c4844fe408e9', 'name': 'crust-permeability', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'earth-and-environmental-sciences', 'id': '550b3d1c-2608-46b4-8e21-47340a0d61d3', 'name': 'earth-and-environmental-sciences', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'engineering', 'id': '3ff6cbc9-08ad-4fd1-aa1e-6676db9d1e1c', 'name': 'engineering', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'evaporation', 'id': '019d67cf-b767-4fe7-b05e-28635fb0a327', 'name': 'evaporation', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'magnesium-sulfate', 'id': '883b89e3-f412-4b4d-81fa-48363b68fa41', 'name': 'magnesium-sulfate', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'salt-precipitation', 'id': 'ff658845-35cf-47b0-a4c3-5c7747ce2ac4', 'name': 'salt-precipitation', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'soil-salinization', 'id': '465dd76c-2b46-4493-916a-bb545f015299', 'name': 'soil-salinization', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Maschita, Johannes, Banerjee, Tanmay, Savasci, Gökcen, Haase, Frederik, Ochsenfeld, Christian, Lotsch, Bettina', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1837', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:16.763035', 'metadata_modified': '2023-05-08T19:13:16.763041', 'name': 'doi-10-18419-darus-1837', 'notes': 'Covalent organic frameworks (COFs) are an extensively studied class of porous materials, which distinguish themselves from other porous polymers in their crystallinity and high degree of modularity, enabling a wide range of applications. COFs are most commonly synthesized solvothermally, which is often a time‐consuming process and restricted to well‐soluble precursor molecules. Synthesis of polyimide‐linked COFs (PI‐COFs) is further complicated by the poor reversibility of the ring‐closing reaction under solvothermal conditions. Herein, we report the ionothermal synthesis of crystalline and porous PI‐COFs in zinc chloride and eutectic salt mixtures. This synthesis does not require soluble precursors and the reaction time is significantly reduced as compared to standard solvothermal synthesis methods. In addition to applying the synthesis to previously reported imide COFs, a new perylene‐based COF was also synthesized, which could not be obtained by the classical solvothermal route. In situ high‐temperature XRPD analysis hints to the formation of precursor-salt adducts as crystalline intermediates, which then react with each other to form the COF.<br>\nAll primary data files of measurements and processed data of the journal article mentioned under related publications from Lotsch group can be found here.<br>\nThis dataset contains all data from analytical measurements including crystal structures, SEM/EDX, FT-IR, NMR, BET plots, PL spectra, PXRD, TEM, and UV-vis absorption of the journal article mentioned under the related publication.', 'num_resources': 1, 'num_tags': 6, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data for: "Ionothermal Synthesis of Imide‐Linked Covalent Organic Frameworks"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Maschita, Johannes'}, {'key': 'creator', 'value': 'Maschita, Johannes'}, {'key': 'date', 'value': '2022-04-01T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-1837'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:04'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '4087ab60-2fdb-4140-8c02-2aad9d4f8be4'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'groups': [{'description': '', 'display_name': 'openaire_data', 'id': 'openaire_data', 'image_display_url': '', 'name': 'openaire_data', 'title': 'openaire_data'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:16.764994', 'format': 'HTML', 'hash': '', 'id': 'a184b9ba-7e3c-4322-9911-1e75de1eb4e8', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:16.753270', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data for: "Ionothermal Synthesis of Imide‐Linked Covalent Organic Frameworks"', 'package_id': 'doi-10-18419-darus-1837', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-1837', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'covalent-organic-framework', 'id': '5a6dcae2-b0ae-424e-84a4-f3c428400320', 'name': 'covalent-organic-framework', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'eutectic-salt-mixtures', 'id': '0f9f4068-9f8e-4b1d-b35a-7e285786cff8', 'name': 'eutectic-salt-mixtures', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'ionothermal-synthesis', 'id': '954315aa-4bdc-4bdb-872d-db1d881dbbd1', 'name': 'ionothermal-synthesis', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'zinc-chloride', 'id': 'affe59a3-6eec-4fc1-9de7-53d3d16344bd', 'name': 'zinc-chloride', 'state': 'active', 'vocabulary_id': None}], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Bruckner, Johanna R., Beurer, Ann-Katrin', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1826', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:16.017760', 'metadata_modified': '2023-05-08T19:13:16.017766', 'name': 'doi-10-18419-darus-1826', 'notes': 'All primary data files of measurements and processed data of the associated journal article can be found here. <br/>\nRaw data from physisorption measurements can be found in the <a href="/dataset.xhtml?persistentId=doi:10.18419/darus-1832">dataset of the Traa group.</a> <br/>\nThe data is structured according to experiment type and the material investigated and contains the following data types: PDF, TXT, PDH, GIF, DS8D, GFRM, XLSX <br/>\nAll data was converted to easily readable data types, e.g. TXT. Additional raw data, namely DS8D and GFRM, can be opened with Pyris Software (Perkin Elmer) or SAXS (Bruker AXS), respectively.', 'num_resources': 1, 'num_tags': 8, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data of Gießelmann/Bruckner group for: "Mechanisms and Intermediates in the True Liquid Crystal Templating Synthesis of Mesoporous Silica Materials"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Bruckner, Johanna R.'}, {'key': 'creator', 'value': 'Bruckner, Johanna R.'}, {'key': 'date', 'value': '2021-05-05T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-1826'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:04'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': 'b46dfc9d-2886-4e66-9e4c-4dbd8da6a07a'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:16.035860', 'format': 'HTML', 'hash': '', 'id': 'aea1c33f-d8ba-47f7-9660-94d0888277ce', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:15.989986', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data of Gießelmann/Bruckner group for: "Mechanisms and Intermediates in the True Liquid Crystal Templating Synthesis of Mesoporous Silica Materials"', 'package_id': 'doi-10-18419-darus-1826', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-1826', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'lyotropic-liquid-crystal', 'id': 'e278bd5c-12a1-4351-a6d1-16ad880ca6f8', 'name': 'lyotropic-liquid-crystal', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'ordered-mesoporous-silica', 'id': 'c7360b58-a44f-4cda-93d8-20c61a28aa4f', 'name': 'ordered-mesoporous-silica', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'physics', 'id': '820fb04d-8f9c-45ca-9a54-9054d91e527b', 'name': 'physics', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'sba-15', 'id': '76b40c27-540b-4844-a974-3b5dcf19b1db', 'name': 'sba-15', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'surfactants', 'id': 'ee1c583b-6735-4491-b64f-ab8d7c4922c0', 'name': 'surfactants', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'x-ray-scattering', 'id': '76745639-fc7e-4785-a44c-4b8db2f78f68', 'name': 'x-ray-scattering', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Grunenberg, Lars, Savasci, Gökcen, Terban, Maxwell, Duppel, Viola, Moudrakovski, Igor, Etter, Martin, Dinnebier, Robert, Ochsenfeld, Christian, Lotsch, Bettina V.', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1813', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:15.577244', 'metadata_modified': '2023-05-08T19:13:15.577249', 'name': 'doi-10-18419-darus-1813', 'notes': '<p>Covalent organic frameworks have emerged as a powerful synthetic platform for installing and interconverting dedicated molecular functions on a crystalline polymeric backbone with atomic precision. Here, we present a novel strategy to directly access amine-linked covalent organic frameworks, which serve as a scaffold enabling pore-wall modification and linkage-interconversion by new synthetic methods based on Leuckart–Wallach reduction with formic acid and ammonium formate. Frameworks connected entirely by secondary amine linkages, mixed amine/imine bonds, and partially formylated amine linkages are obtained in a single step from imine-linked frameworks or directly from corresponding linkers in a one-pot crystallization-reduction approach. The new, 2D amine-linked covalent organic frameworks, rPI-3-COF, rTTI-COF, and rPy1P-COF, are obtained with high crystallinity and large surface areas. Secondary amines, installed as reactive sites on the pore wall, enable further postsynthetic functionalization to access tailored covalent organic frameworks, with increased hydrolytic stability, as potential heterogeneous catalysts.</p>\n\n<p>This dataset contains all data from analytical measurements including FT-IR spectra, calculated IR modes, raw XRD patterns, 1H, 13C, 15N and 1H/13C-HETCOR ssNMR spectra, N2 sorption isotherms, pore-size distributions, BET plots, SEM and TEM images, SEM-EDX spectra, quantum-chemically optimized structures, calculated NMR chemical shifts, reduced total scattering patterns, PDF analysis and Rietveld structure refinements of the journal article mentioned under the related publication.</p>\n\nOpen *.cif and *.xyz files with a visualization software (see http://ww1.iucr.org/iucr-top/cif/), *.raw files with WinXPOW, *.sp files with PerkinElmer Spectrum software, *.mnova files with MestReNova, *.fq/.gr/iq/sq files with a text editor, *.cdr files with CorelDraw 2020 and *.pro files with TOPAS.', 'num_resources': 1, 'num_tags': 3, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Replication data for "Amine-Linked Covalent Organic Frameworks as a Platform for Postsynthetic Structure Interconversion and Pore-Wall Modification"', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Grunenberg, Lars'}, {'key': 'creator', 'value': 'Grunenberg, Lars'}, {'key': 'date', 'value': '2022-04-04T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-1813'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:04'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '765f3424-0e05-498a-a5cc-f098330e9f59'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'groups': [{'description': '', 'display_name': 'openaire_data', 'id': 'openaire_data', 'image_display_url': '', 'name': 'openaire_data', 'title': 'openaire_data'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:13:15.583944', 'format': 'HTML', 'hash': '', 'id': '12524a6b-6972-458d-9be9-ecfc38cfe3c7', 'last_modified': None, 'metadata_modified': '2023-05-08T19:13:15.570167', 'mimetype': None, 'mimetype_inner': None, 'name': 'Replication data for "Amine-Linked Covalent Organic Frameworks as a Platform for Postsynthetic Structure Interconversion and Pore-Wall Modification"', 'package_id': 'doi-10-18419-darus-1813', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-1813', 'url_type': None}], 'tags': [{'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'covalent-organic-framework', 'id': '5a6dcae2-b0ae-424e-84a4-f3c428400320', 'name': 'covalent-organic-framework', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Groos, Jonas, Hauser, Philipp Manuel, Koy, Maximilian, Frey, Wolfgang, Buchmeiser, Michael', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1811', 'isopen': False, 'language': 'English', 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:15.116033', 'metadata_modified': '2023-05-08T19:13:15.116038', 'name': 'doi-10-18419-darus-1811', 'notes': 'All primary data files of measurements and processed data of the journal article from Buchmeiser group can be found here. Procedures, reaction conditions and used analytical equipment is discussed in detail in the experimental section or the supporting information of the paper. Productivities in alkyne metathesis reactions were examined via gas-chromatography / mass spectrometry (GC-MS) analysis and can be found in the GC-MS folder. Novel complexes were examined via nuclear magnetic resonance (NMR) spectroscopy and the spectra can be found in the NMR folder. The NMR folder also contains NMR experiments mentioned in the paper and shown in the Supplementary Information. NMR Spectra are named according to the numbering in the publication. All crystal data mentioned in the paper can be found in the related datasets. NMR data is in the folder NMR divided in NMR experiments and compounds which consists of the NMR spectra of pure compounds. 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