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[{'author': 'Ziegler, Felix', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-832', 'isopen': False, 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:14:23.488051', 'metadata_modified': '2023-05-08T19:14:23.488056', 'name': 'doi-10-18419-darus-832', 'notes': 'This paper addresses the synthesis of macrocyclic molecules by a spatial confinement effect in SBA-15. Various aspects such as concentration dependence, substrate size and temperature dependence have been discussed.<br><br> \n\nIn the attached data you will find all NMR spectra of the performed reactions as well as the sorption measurements, ICP analyses, elemental analyses, Maldi-TOF and SEM pictures. All data are sorted according to the labeling in the paper.<br><br>\n\nAll primary data files and processed data of the journal article from the Buchmeiser group and links to related data sets from other groups.', 'num_resources': 1, 'num_tags': 5, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 'Chemistry collection from DaRUS, the data repository of the University of Stuttgart.', 'image_url': 'logoDarusKreis.png', 'created': '2023-05-03T09:01:04.791551', 'is_organization': True, 'approval_status': 'approved', 'state': 'active'}, 'owner_org': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'private': False, 'related_molecule': [], 'state': 'active', 'title': 'Olefin Metathesis in Confined Geometries: A Biomimetic Approach toward Selective Macrocyclization Data Buchmeiser', 'type': 'dataset', 'extras': [{'key': 'contributor', 'value': 'Ziegler, Felix'}, {'key': 'creator', 'value': 'Ziegler, Felix'}, {'key': 'date', 'value': '2020-12-23T00:00:00'}, {'key': 'identifier', 'value': 'https://doi.org/10.18419/darus-832'}, {'key': 'metadata_modified', 'value': '2022-11-29T01:00:03'}, {'key': 'relation', 'value': 'Felix Ziegler, Johannes Teske, Iris Elser, Michael Dyballa, Wolfgang Frey, Hamzeh Kraus, Niels Hansen, Julia Rybka, Ulrich Tallarek, Michael R. Buchmeiser CCDC 1942469: Experimental Crystal Structure Determination, 2019, DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc23699y">10.5517/ccdc.csd.cc23699y</a>'}, {'key': 'set_spec', 'value': 'all'}, {'key': 'harvest_object_id', 'value': '8a7e8a72-295f-4400-83e5-15abf928ef90'}, {'key': 'harvest_source_id', 'value': '8ba5ef26-d024-46cd-8099-94f1e74e7a36'}, {'key': 'harvest_source_title', 'value': 'Darus Test Harvest'}], 'resources': [{'cache_last_updated': None, 'cache_url': None, 'created': '2023-05-08T19:14:23.489548', 'format': 'HTML', 'hash': '', 'id': 'ddab5dd7-345f-462e-bc1c-096ad5087484', 'last_modified': None, 'metadata_modified': '2023-05-08T19:14:23.472814', 'mimetype': None, 'mimetype_inner': None, 'name': 'Olefin Metathesis in Confined Geometries: A Biomimetic Approach toward Selective Macrocyclization Data Buchmeiser', 'package_id': 'doi-10-18419-darus-832', 'position': 0, 'resource_type': 'HTML', 'size': None, 'state': 'active', 'url': 'https://doi.org/10.18419/darus-832', 'url_type': None}], 'tags': [{'display_name': 'catalysis', 'id': '109d3c51-8485-4605-ad00-c576d7092a7a', 'name': 'catalysis', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'chemistry', 'id': '20e4e978-2a22-4286-a18b-4ae22d1ffca1', 'name': 'chemistry', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'confinement', 'id': '6cb7505c-f92e-435f-a1dc-e7542d4a061a', 'name': 'confinement', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'experimental-data', 'id': '2468cb76-4757-4ec7-be40-8da1b05b5f1c', 'name': 'experimental-data', 'state': 'active', 'vocabulary_id': None}, {'display_name': 'metathesis', 'id': '62ec03a6-9504-48c7-9261-c43ce49d375b', 'name': 'metathesis', 'state': 'active', 'vocabulary_id': None}], 'groups': [], 'relationships_as_subject': [], 'relationships_as_object': []}, {'author': 'Ziegler, Felix', 'author_email': None, 'creator_user_id': '1be646ae-ab26-47b8-8835-e4b27f11961e', 'id': 'doi-10-18419-darus-1690', 'isopen': False, 'license_id': '', 'license_title': '', 'maintainer': 'DaRUS', 'maintainer_email': None, 'metadata_created': '2023-05-08T19:13:01.391059', 'metadata_modified': '2023-05-08T19:13:01.391064', 'name': 'doi-10-18419-darus-1690', 'notes': 'The use of a 2nd-generation Hoveyda-Grubbs-type catalyst immobilized inside mesoporous silica for the application in selective macro(mono)cyclization (MMC) of an alpha,omega-diene under spatially confined and continuous-flow conditions.\n<br>Data you will find:\n<br>NMR-Data for the determination of conversion and selectivity of the macrocyclization.\n<br>MALDI results for the different samples where you can see the different oligomer products.\n<br>BET sorption data for the determination of surface area pore volume and pore distribution.', 'num_resources': 1, 'num_tags': 6, 'organization': {'id': '9a7d2a53-21f6-412a-afb9-a15122df0640', 'name': 'darus', 'title': 'DaRUS', 'type': 'repository', 'description': 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| ungettext |
<function ungettext at 0x7f0d1e2eb1e0> |
