@prefix bfo: <http://purl.obolibrary.org/obo/BFO_> .
@prefix chebi: <http://purl.obolibrary.org/obo/CHEBI_> .
@prefix chemdcatap: <https://w3id.org/nfdi-de/dcat-ap-plus/chemistry/> .
@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix obi: <http://purl.obolibrary.org/obo/OBI_> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix schema1: <http://schema.org/> .
@prefix sio: <http://semanticscience.org/resource/SIO_> .

<doi-10-18419-darus-1694> a chemdcatap:SubstanceSampleCharacterizationDataset ;
    dct:conformsTo [ a dct:Standard ;
            dct:identifier <https://docs.nmrxiv.org/submission-guides/data-model/spectra.html> ] ;
    dct:language <http://id.loc.gov/vocabulary/iso639-1/en> ;
    dct:publisher <https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> ;
    prov:wasGeneratedBy <doi-10-18419-darus-1694#measurement> .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694> a dcat:Dataset ;
    dct:description """The influence of the structure of cationic molybdenum imido alkylidene N-heterocyclic carbene\r
(NHC) catalysts, i. e. of [Mo(N-2-tert-butyl-C6H4) (CHCMe2Ph)(NHC)X+ B(ArF)4\r
] (NHC=1,3-di(2-Pr)\r
imidazol-2-ylidene (iPr), 1,3-dimesitylimidazol-2-ylidene (IMes); X=pyrrolide, OCH(CF3)2, B(ArF)4\r
 =\r
tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) and of [Mo(N-3,5-Me2-C6H3)(CHCMe2Ph)(NHC)(CH3CN)X+\r
B(ArF)4\r
] (NHC=1,3-dimesitylimidazol-2-ylidene, 1,3-dimesitylimidazolin-2-ylidene (IMesH2); X=CF3SO3,\r
OCPh(CF3)2) on E/Z-selectivity in the ring-opening cross-metathesis (ROCM) of endo, endo-2,3-\r
dicarbomethoxynorborn-5-ene (endo, endo-DCMNBE), exo, exo-2,3-dicarbomethoxynorborn-5-ene (exo, exo-\r
DCMNBE), endo, exo-2,3-dicarbomethoxynorborn-5-ene ((+) DCMNBE) and 2,3-exo,exo-bis(acetoxymethyl)-\r
7-oxabicyclo[2.2.l]hept-5-ene (7-oxa-NBE) with 1-pentene, styrene, allyltrimethylsilane, allyl benzyl ether,\r
allyl phenyl ether and allyl ethyl ether has been studied. With the exception of the ROCM reaction of endo,\r
endo-DCMNBE with styrene, all other ROCM reactions of endo, endo-DCMNBE proceeded under\r
thermodynamic control without any post-metathesis isomerization reactions with full retention of the\r
configuration of the newly formed 1,2-disubstituted double bond as confirmed by kinetic studies. Similar\r
accounts for selected homometathesis reactions. Catalyst structure-selectivity correlations based on the buried\r
volume, Vbur, of the N-imido ligand are presented. <br/>\r
\r
All primary data files and processed data of the journal article from <a href="https://doi.org/10.1002/adsc.201900979">Buchmeiser group</a>.""" ;
    dct:identifier "doi-10-18419-darus-1694" ;
    dct:subject <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#sample> ;
    dct:title "Data for: Stereoselective Olefin Ring-Opening Cross Metathesis Catalyzed by Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes" ;
    prov:wasGeneratedBy <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#measurement> .

<http://id.loc.gov/vocabulary/iso639-1/en> a dct:LinguisticSystem .

obi:0000070 a schema1:DefinedTerm ;
    schema1:name "assay" .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#measurement> a obi:0000070,
        prov:Activity ;
    prov:used <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#sample> .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#sample_compound> a chebi:23367 .

<https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> a foaf:Organization ;
    foaf:name "DaRUS" .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#sample> a sio:001378 ;
    bfo:0000051 <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1694#sample_compound> ;
    dct:title "evaluated sample" .