@prefix adms: <http://www.w3.org/ns/adms#> .
@prefix bfo: <http://purl.obolibrary.org/obo/BFO_> .
@prefix chebi: <http://purl.obolibrary.org/obo/CHEBI_> .
@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dcatap: <http://data.europa.eu/r5r/> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix obi: <http://purl.obolibrary.org/obo/OBI_> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix schema1: <http://schema.org/> .
@prefix sio: <http://semanticscience.org/resource/SIO_> .
@prefix skos: <http://www.w3.org/2004/02/skos/core#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705> a dcat:Dataset ;
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    dct:conformsTo [ a dct:Standard ;
            dct:description "https://w3id.org/nfdi-de/dcat-ap-plus/chemistry/" ;
            dct:title "ChemDCAT-AP" ] ;
    dct:creator [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Schowner" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Buchmeiser" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Frey" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Michael" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Wolfgang" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "A human being." ;
                    skos:prefLabel "person" ] ;
            foaf:name "Roman" ] ;
    dct:description """Data on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl‐substituted imido ligands, highly basic 6‐Mes (6‐Mes = 1,3‐dimesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐ylidene) NHC ligands and the preparation of the first representatives of cationic 14‐electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands.  <br/>\r
Synthetic approaches and data are presented in the research article. <br/>\r
Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added.\r
Crystallographic data was published in the CCDC as stated under related datasets . <br/> \r
This dataset contains the following data types: NMR data (raw data, Bruker-zip files)""" ;
    dct:identifier "https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705" ;
    dct:issued "2023-05-08"^^xsd:date ;
    dct:language [ a dct:LinguisticSystem ;
            dct:description "http://id.loc.gov/vocabulary/iso639-1/en" ;
            dct:title "en" ] ;
    dct:modified "2023-05-08"^^xsd:date ;
    dct:publisher [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
                    dct:description "http://purl.org/adms/publishertype/Academia-ScientificOrganisation" ;
                    skos:prefLabel "Academia/Scientific organisation" ] ;
            foaf:name "DaRUS" ] ;
    dct:subject <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#sample> ;
    dct:title "Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N‐Heterocyclic Carbene Complexes" ;
    adms:identifier [ a adms:Identifier ;
            dct:description "The id of this dataset within the NFDI4Chem Search Service (https://search.nfdi4chem.de/)" ;
            dct:title "Search Service ID" ;
            skos:notation "https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705" ] ;
    prov:wasGeneratedBy <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#measurement> .

obi:0000070 a schema1:DefinedTerm ;
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<https://creativecommons.org/licenses/by/4.0> a <http://data.europa.eu/eli/ontology#LegalResource> ;
    dct:title "Attribution 4.0 International (CC BY 4.0)" .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#measurement> a obi:0000070,
        prov:Activity ;
    dct:description "The kind of activity/process used to generate the dataset" ;
    prov:used <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#sample> .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#sample_compound> a chebi:23367 .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#sample> a sio:001378 ;
    bfo:0000051 <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-1705#sample_compound> ;
    dct:title "evaluated sample" .

