@prefix adms: <http://www.w3.org/ns/adms#> .
@prefix bfo: <http://purl.obolibrary.org/obo/BFO_> .
@prefix chebi: <http://purl.obolibrary.org/obo/CHEBI_> .
@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dcatap: <http://data.europa.eu/r5r/> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix obi: <http://purl.obolibrary.org/obo/OBI_> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix schema1: <http://schema.org/> .
@prefix sio: <http://semanticscience.org/resource/SIO_> .
@prefix skos: <http://www.w3.org/2004/02/skos/core#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:conformsTo [ a dct:Standard ;
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            dct:title "ChemDCAT-AP" ] ;
    dct:creator [ a foaf:Agent ;
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                    dct:description "A human being." ;
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            foaf:name "Panyam" ],
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            foaf:name "Pradeep Kumar Reddy" ],
        [ a foaf:Agent ;
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            foaf:name "Michal" ],
        [ a foaf:Agent ;
            dct:type [ a skos:Concept ;
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                    skos:prefLabel "person" ] ;
            foaf:name "Buchmeiser" ],
        [ a foaf:Agent ;
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            foaf:name "Boshra" ],
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    dct:description """<p>Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes. Selected catalysts were immobilized within the mesopores of SBA-15. The confinement effects either provided by the ligands or the mesoporous support have been studied and allow for hydrosilylation with β(Z)-selectivity of up to 100 % with both Rh(I) and Rh(III) complexes.</p>

<p>All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here.</p>

The  following dataset contains the following data types: NMR Spectra and HRMS data. The Crystal data (see related datasets) is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).""" ;
    dct:identifier "https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473" ;
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            foaf:name "DaRUS" ] ;
    dct:subject <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473#sample> ;
    dct:title "Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes" ;
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            dct:title "Search Service ID" ;
            skos:notation "https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473" ] ;
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    dct:title "Attribution 4.0 International (CC BY 4.0)" .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473#measurement> a obi:0000070,
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<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473#sample_compound> a chebi:23367 .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473#sample> a sio:001378 ;
    bfo:0000051 <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-2473#sample_compound> ;
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