@prefix bfo: <http://purl.obolibrary.org/obo/BFO_> .
@prefix chebi: <http://purl.obolibrary.org/obo/CHEBI_> .
@prefix chemdcatap: <https://w3id.org/nfdi-de/dcat-ap-plus/chemistry/> .
@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix obi: <http://purl.obolibrary.org/obo/OBI_> .
@prefix prov: <http://www.w3.org/ns/prov#> .
@prefix schema1: <http://schema.org/> .
@prefix sio: <http://semanticscience.org/resource/SIO_> .

<https://doi.org/https://doi.org/10.18419/DARUS-3316> a dcat:Dataset,
        chemdcatap:SubstanceSampleCharacterizationDataset ;
    dct:conformsTo [ a dct:Standard ;
            dct:identifier <https://docs.nmrxiv.org/submission-guides/data-model/spectra.html> ] ;
    dct:description """<p>As covalent organic frameworks (COFs) are coming of age, the lack of effective approaches to achieve crystalline and centimeter-scale-homogeneous COF films remains a significant bottleneck toward advancing the application of COFs in optoelectronic devices. Here, we present the synthesis of colloidal COF nanoplates, with lateral sizes of ∼200 nm and average heights of 35 nm, and their utilization as photocathodes for solar hydrogen evolution. The resulting COF nanoplate colloid exhibits a unimodal particle-size distribution and an exceptional colloidal stability without showing agglomeration after storage for 10 months and enables smooth, homogeneous, and thickness-tunable COF nanofilms via spin coating. Photoelectrodes comprising COF nanofilms were fabricated for photoelectrochemical (PEC) solar-to-hydrogen conversion. By rationally designing multicomponent photoelectrode architectures including a polymer donor/COF heterojunction and a hole-transport layer, charge recombination in COFs is mitigated, resulting in a significantly increased photocurrent density and an extremely positive onset potential for PEC hydrogen evolution (over +1 V against the reversible hydrogen electrode), among the best of classical semiconductor-based photocathodes. This work thus paves the way toward fabricating solution-processed large-scale COF nanofilms and heterojunction architectures and their use in solar-energy-conversion devices.</p>

<p>All primary data files of measurements and processed data of the journal article mentioned under related publications from Lotsch group can be found here.</p>

The  data is structured according to figures and schemes in the research article and contains the following data types: XRD patterns (*.raw), AFM images (*.ibw), Nitrogen isotherm profiles (*.qps), dynamic light scattering data (*.dts), TEM images (*.dm3), ChemDraw files (*.cdxml), NMR data (*.jdf, *.mnova), python jupyter files (*.ipynb), CorelDraw files (*.cdr), SEM images (*.tif), electrochemistry data (*.paax), origin files (*.opju), COF structure models (*.cif), and FT-IR spectra (*.sp).""" ;
    dct:identifier "https://doi.org/https://doi.org/10.18419/DARUS-3316" ;
    dct:language <http://id.loc.gov/vocabulary/iso639-1/en> ;
    dct:publisher <https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> ;
    dct:subject <https://doi.org/https://doi.org/10.18419/DARUS-3316#sample> ;
    dct:title "Replication data of Lotsch group for: \"Covalent Organic Framework Nanoplates Enable Solution-Processed Crystalline Nanofilms for Photoelectrochemical Hydrogen Evolution\"" ;
    prov:wasGeneratedBy <https://doi.org/https://doi.org/10.18419/DARUS-3316#measurement> .

<http://id.loc.gov/vocabulary/iso639-1/en> a dct:LinguisticSystem .

obi:0000070 a schema1:DefinedTerm ;
    schema1:name "assay" .

<https://doi.org/https://doi.org/10.18419/DARUS-3316#measurement> a obi:0000070,
        prov:Activity ;
    prov:used <https://doi.org/https://doi.org/10.18419/DARUS-3316#sample> .

<https://doi.org/https://doi.org/10.18419/DARUS-3316#sample_compound> a chebi:23367 .

<https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> a foaf:Organization ;
    foaf:name "DaRUS" .

<https://doi.org/https://doi.org/10.18419/DARUS-3316#sample> a sio:001378 ;
    bfo:0000051 <https://doi.org/https://doi.org/10.18419/DARUS-3316#sample_compound> ;
    dct:title "evaluated sample" .