@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:description """Herein, we report a facile postsynthetic linkage conversion method giving synthetic access to nitrone-linked covalent organic frameworks (COFs) from imine- and amine-linked COFs. The new two-dimensional (2D) nitrone-linked covalent organic frameworks, NO-PI-3-COF and NO-TTI-COF, are obtained with high crystallinity and large surface areas. Nitrone-modified pore channels induce condensation of water vapor at 20% lower humidity compared to their amine- or imine-linked precursor COFs. Thus, the topochemical transformation to nitrone linkages constitutes an attractive approach to postsynthetically fine-tune water adsorption properties in framework materials.

Open *.cif files with a visualization software (see http://ww1.iucr.org/iucr-top/cif/), *.raw files with WinXPOW, *.txt, *.csv, *.xyd and *.aif files with a text editor, *.sp files with PerkinElmer Spectrum software, *.mnova files with MestReNova, and *.pro files with TOPAS.""" ;
    dct:identifier "doi-10-18419-darus-3658" ;
    dct:issued "2025-07-29T12:23:19.397996"^^xsd:dateTime ;
    dct:language "English" ;
    dct:modified "2025-11-04T16:13:20.284106"^^xsd:dateTime ;
    dct:publisher <https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> ;
    dct:title "Replication data of Lotsch group for: \"Postsynthetic Transformation of Imine- into Nitrone-Linked Covalent Organic Frameworks for Atmospheric Water Harvesting at Decreased Humidity\"" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "DaRUS" ] ;
    dcat:distribution <https://search.nfdi4chem.de/dataset/doi-10-18419-darus-3658/resource/9373b28b-2a5f-49f6-b1d1-162eabaa4642> ;
    dcat:keyword "adsorption",
        "chemistry",
        "covalent-organic-frameworks",
        "dataset",
        "materials",
        "nitrogen-compounds",
        "oxidation" ;
    dcat:landingPage <https://doi.org/10.18419/DARUS-3658> .

<https://search.nfdi4chem.de/dataset/doi-10-18419-darus-3658/resource/9373b28b-2a5f-49f6-b1d1-162eabaa4642> a dcat:Distribution ;
    dct:format "HTML" ;
    dct:issued "2025-11-04T16:13:20.316214"^^xsd:dateTime ;
    dct:modified "2025-11-04T16:13:20.290694"^^xsd:dateTime ;
    dct:title "Replication data of Lotsch group for: \"Postsynthetic Transformation of Imine- into Nitrone-Linked Covalent Organic Frameworks for Atmospheric Water Harvesting at Decreased Humidity\"" ;
    dcat:accessURL <https://doi.org/10.18419/DARUS-3658> .

<https://search.nfdi4chem.de/organization/9a7d2a53-21f6-412a-afb9-a15122df0640> a foaf:Organization ;
    foaf:name "DaRUS" .