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Short-RInChIKey=SA-FUHFF-UHFFFADPSC-OHIGKOFNMG-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of methyl(triphenyl)phosphonium;iodide (1.37 g, 3.38 mmol, 1.15 equiv) in dry THF (30.0 mL), n-butyllithium solution (188 mg, 1.18 mL, 2.94 mmol, 2.50 M in... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-DIWSFGZULS-UHFFFADPSC-NUHFF-NBIDU-NUHFF-ZZZ Dataset
Potassium;gold(3+);tetrachloride (152 mg, 402 μmol, 2.01 equiv) was placed in a microwave-compatible flask, a solution containing 5,10,15,20-tetrakis(4-pyridyl)porphyrin (124... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-GSCCFQIFSQ-UHFFFADPSC-NUHFF-FPSPN-NUHFF-ZZZ Dataset
A mixture of AgOTf (20.34 mg, 0.08 mmol) and [Ru2(η 6 -p-cymene)2(dhbq)Cl2] (27.2 mg, 0.04 mmol) in methanol (8 mL) was stirred at rt for 3 hrs, then filtered. To the red... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-GXNWSCMDKK-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
For a registration in the database Chemotion, the information given below was retrieved and reworked from the publication: Asymmetric synthesis of deuterated and fluorinated... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-DOMRLGGERF-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
For a registration in the Chemotion repository, the information given below was retrieved and reworked from the publication: Asymmetric synthesis of deuterated and fluorinated... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-BEGUWTIVAN-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
4,5-Dibromobenzene-1,2-diamine (1.00 g, 3.76 mmol, 1.00 equiv), phenylboronic acid (1.01 g, 8.27 mmol, 2.20 equiv), tetrakis(triphenylphosphine)palladium(0) (86.9 mg, 75.2... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-DNMLVVBQWL-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
For a registration in the Chemotion repository, the information given below was retrieved and reworked from the publication: Asymmetric synthesis of deuterated and fluorinated... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-DSMMAQWRRJ-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
3-(Trifluoromethyl)-1H-quinoxalin-2-one (100 mg, 467 μmol, 1.00 equiv) was dissolved in phosphoryl chloride (2.15 g, 1.31 mL, 14.0 mmol, 30.0 equiv). Few drops of DMF were... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-BYHVGQHIAF-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
1H-quinoxalin-2-one (3.00 g, 20.5 mmol, 1.00 equiv) was dissolved in phosphoryl chloride (36.2 g, 22.0 mL, 236 mmol, 11.5 equiv). The reaction was stirred for 4 h at 100 °C... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-OYFFSPILVQ-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
9H-Carbazole (500 mg, 2.99 mmol, 1.00 equiv) and zinc dichloride (856 mg, 6.28 mmol, 2.10 equiv) were dried in a vial. Nitromethane (10 mL) was added under argon atmosphere. A... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-VSSFGRBIDN-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of 3-phenyl-1H-quinoxalin-2-one (1.00 g, 4.50 mmol, 1.00 equiv) in toluene (50 mL) was added tetrabutylazanium;bromide (1.89 g, 5.85 mmol, 1.30 equiv) and... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-HCWOOULLNK-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
3-Tert-butyl-1H-quinoxalin-2-one (1.00 g, 4.94 mmol, 1.00 equiv) was dissolved in phosphoryl chloride (11.4 g, 6.93 mL, 74.2 mmol, 15.0 equiv). The reaction was stirred at 100... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-PECAOKZHOR-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of 9H-carbazole (1.00 g, 5.98 mmol, 1.00 equiv) in acetic acid (20.0 mL) was added potassium iodide (1.33 g, 8.04 mmol, 1.34 equiv), then, while stirring, was... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-NTUCWBPMVK-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of 3,6-ditert-butyl-9H-carbazole (200 mg, 716 μmol, 1.00 equiv) in acetic acid (12 mL) was added molecular bromine (240 mg, 77.5 μL, 1.50 mmol, 2.10 equiv). The... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-KHQNNRFYGO-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
A suspension of (Z)-2,3-diaminobut-2-enedinitrile (216 mg, 2.00 mmol, 1.00 equiv), 1,2-diphenylethane-1,2-dione (420 mg, 2.00 mmol, 1.00 equiv) and acetic acid (210 mg, 200... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-GWQUFNJIVJ-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of (Z)-2,3-diaminobut-2-enedinitrile (200 mg, 1.85 mmol, 1.00 equiv) in THF (8 mL) were slowly added methyl 2-oxopropanoate (208 mg, 184 μL, 2.04 mmol, 1.10... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-TTXGKCVKGX-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
N-[4,5-Dibromo-2-(tosylamino)phenyl]-4-methyl-benzenesulfonamide (20.7 g, 36.0 mmol, 1.00 equiv) was dissolved in sulfuric acid (73.6 g, 40.0 mL, 750 mmol, 20.8 equiv). The... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-PCMKGEAHIZ-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
3,6-Dibromo-9H-carbazole (299 mg, 920 μmol, 1.00 equiv), phenylboronic acid (190 mg, 1.56 mmol, 1.69 equiv), dipotassium;carbonate (255 mg, 1.85 mmol, 2.01 equiv) and... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-NOGLKXWLUD-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of benzene-1,2-diamine (1.00 g, 9.25 mmol, 1.00 equiv) in THF (20 mL) was added methyl 3,3,3-trifluoro-2-oxopropanoate (1.73 g, 1.13 mL, 11.1 mmol, 1.20 equiv).... -
Short-RInChIKey=SA-FUHFF-UHFFFADPSC-FGAFCTKXFA-UHFFFADPSC-NUHFF-NUHFF-NUHFF-ZZZ Dataset
To a solution of 9H-carbazole (500 mg, 2.99 mmol, 1.00 equiv) and potassium hydroxide (252 mg, 4.49 mmol, 1.50 equiv) in acetone (50 mL) was added 1-bromoheptane (643 mg, 564...
