Dataset

Experimental Data to the publication ""Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands"

Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and results of stopped-flow UV/Vis spectroscic measurements were deposited.

Chemical Info

Data and Resources

Metadata Information

Field Value
DOI https://dx.doi.org/10.22000/snmphx276tt041sa
License URL https://creativecommons.org/licenses/by-sa/4.0/legalcode
Source
Version
Author Seitz, Tobias, Walbeck, Marcel , Hoffmann, Alexander, Herres-Pawlis, Sonja
Maintainer RWTH Aachen University
Language {eng}
MetadataCreated 2025-01-29T14:06:50.249839
MetadataModified 2025-01-29T14:06:50.249844
MetadataPublished
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Measurement Technique {"The stopped-flow measurements were performed with a HI-TECH Scientific SF-61SX2 device with a diode array detector. The optical light path for transmission of the quartz glass cuvette was 10 mm. ","The measurements were performed with a METROHM AUTOLAB PGSTAT 101 potentiostat using a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), a Pt wire as counter electrode and an Ag/AgCl (in saturated ethanolic LiCl) reference electrode. The measurements were performed in MeCN and 100 mmol/L NBu4PF6 with a sample concentration of 1 mmol/L at room temperature. Ferrocene was added as an internal standard after the measurements of the sample and all potentials are referenced relative to the Fc/Fc+ potential. Cyclic voltammograms were measured with 200 mV·s–1, 100 mV·s–1, 50 mV·s–1 and 20 mV·s–1. ",Instrument,Instrument}
Measurement Variables
Data-Source Molecule ID Data-Source
No additional information available for this Dataset.